Thanks for your reply.
Yeah, we drained it all. Coolant looked in good condition, no scum or flakey bits! Replaced it with new stuff. Left the top hose off and filled in till it came out the hose hole, refitted the hose and added a little bit more. We originally had it filled to the top of the chamber on the top of the radiator, which i'm now assuming is an expansion tank?
Any more idea's?